The Synthesis of α-Azidoesters and Geminal Triazides

The use of organic azides is ubiquitous in the functionalization
of biomolecules through click chemistry, and also has
many applications in materials science. These aspects led
Professor Stefan Kirsch and his research group at the
Bergische Universität Wuppertal (Germany) to develop an
interest in the direct installation of the azide moiety through
the oxidative functionalization of enolizable compounds with
a simple azide source, preferably sodium azide.

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